Function Settings
The familiar pinout diagram for Pico GPIO function settings:

See the datasheets for more details:
Pico - RP2040 Datasheet 2.19.2 Function select

Pico 2 - RP2350 Datasheet 9.4. Function select

Each function is assigned a number from F0 to F31, with F31 being the null function (no assignment).
The gpio command in pico-jxgLABO uses the func subcommand to set the function. Available function names:
Pico - spi, uart, i2c, pwm, sio, pio0, pio1, clock, usb, xip, null
Pico 2 - spi, uart, uart-aux, i2c, pwm, sio, pio0, pio1, pio2, clock, usb, hstx, xip-cs1, coresight-trace, null
For example, to set all available GPIOs to PWM function:
L:/>gpio 0- func:pwm
GPIO0 lo func:PWM0 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO1 lo func:PWM0 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO2 lo func:PWM1 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO3 lo func:PWM1 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO4 lo func:PWM2 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO5 lo func:PWM2 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO6 lo func:PWM3 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO7 lo func:PWM3 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO8 lo func:PWM4 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO9 lo func:PWM4 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO10 lo func:PWM5 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO11 lo func:PWM5 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO12 lo func:PWM6 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO13 lo func:PWM6 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO14 lo func:PWM7 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO15 lo func:PWM7 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO16 lo func:PWM0 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO17 lo func:PWM0 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO18 lo func:PWM1 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO19 lo func:PWM1 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO20 lo func:PWM2 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO21 lo func:PWM2 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO22 lo func:PWM3 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO23*lo func:------ dir:in pull:down drive:4mA slew:slow hyst:on
GPIO24*lo func:------ dir:in pull:down drive:4mA slew:slow hyst:on
GPIO25*lo func:------ dir:in pull:down drive:4mA slew:slow hyst:on
GPIO26 lo func:PWM5 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO27 lo func:PWM5 B dir:in pull:down drive:4mA slew:slow hyst:on
GPIO28 lo func:PWM6 A dir:in pull:down drive:4mA slew:slow hyst:on
GPIO29*lo func:------ dir:in pull:down drive:4mA slew:slow hyst:on
Reviewing all available assignments occasionally may help you find more convenient settings.